Most water types you are going to have a little build up from hard water. Removing Hard Water from anything but natural stone. Don't use vinegar on stone. But if you have a sink that has it around the base of the facet you can place a moist towel soaked in vinegar around the base of it.

After about 20 minutes you can remove it and scrub off most of it. If it still needs more touching up then you can place it back on there and wait another 20 minutes it should get most of it off. Just make sure you are keeping an eye on it and testing a small area first. This link will take you to the full story of what you can use it on.

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